When sodium reacts with water, it undergoes a highly exothermic reaction, producing hydrogen gas and sodium hydroxide. This reaction is represented by the chemical equation:
2Na(s)+2H2O(l)→2NaOH(aq)+H2(g)

In this equation, Na(s) represents solid sodium, H2O(l) represents liquid water, NaOH(aq) represents aqueous sodium hydroxide, and H2(g) represents hydrogen gas.
The reaction between sodium and water is extremely vigorous and exothermic, often leading to the immediate formation of hydrogen gas and sodium hydroxide, along with the release of a significant amount of heat. This heat is sufficient to ignite the hydrogen gas, causing it to burn with a characteristic orange flame. The reaction is highly exothermic because the formation of the strong bonds in the products (sodium hydroxide and hydrogen gas) releases more energy than is required to break the bonds in the reactants (sodium and water).
This reaction is also highly exothermic because sodium has a strong tendency to lose its outermost electron, becoming a positively charged sodium ion (Na+). When sodium comes into contact with water, it rapidly donates its outer electron to a water molecule, forming sodium ions (Na+) and hydroxide ions (OH-) in the process. These reactions release a large amount of energy, which further accelerates the reaction and leads to the rapid formation of hydrogen gas and sodium hydroxide.
The reaction between sodium and water is so vigorous that it must be conducted with caution, as it can lead to splattering of hot, caustic sodium hydroxide solution and the ignition of the hydrogen gas produced. Therefore, sodium is typically stored under oil to prevent it from coming into contact with moisture in the air, and any reactions with water are carefully controlled in laboratory settings.
This reaction is not only important from a chemical standpoint but also has practical applications. For example, it is often used in laboratories to generate hydrogen gas, which can be collected and used in various experiments or as a fuel source. Additionally, the formation of sodium hydroxide as a product of this reaction is industrially significant, as sodium hydroxide is widely used in the manufacture of various chemicals, including paper, textiles, and cleaning products. Therefore, understanding the reaction between sodium and water is crucial for both theoretical and practical purposes in the field of chemistry.
More Informations
The reaction between sodium and water is a classic example of a metal reacting with a non-metallic compound to form an ionic compound and a gas. This type of reaction is known as a single displacement or replacement reaction, where the more reactive metal (sodium) displaces the less reactive hydrogen from the water molecule.
Sodium is an alkali metal, belonging to group 1 of the periodic table, and is highly reactive due to its tendency to lose its outermost electron to achieve a stable electron configuration. When solid sodium comes into contact with water, it rapidly reacts to form sodium hydroxide and hydrogen gas. The overall reaction can be broken down into several steps:
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Dissociation of water:
H2O(l)→H(aq)++OH(aq)−
In water, a small fraction of molecules dissociate into positively charged hydrogen ions (H+) and negatively charged hydroxide ions (OH-). This dissociation of water molecules is what makes water a good conductor of electricity. -
Ionization of sodium:
2Na(s)→2Na(aq)++2e−
Sodium atoms lose their outermost electron to form sodium ions (Na+). This process releases energy because the sodium ion has a lower energy state than the neutral sodium atom. -
Reaction between sodium ions and water:
2Na(aq)++2H2O(l)→2NaOH(aq)+H2(g)
The sodium ions produced in the previous step react with water molecules. Each sodium ion donates one electron to a water molecule, resulting in the formation of sodium hydroxide (NaOH) and hydrogen gas (H2).
The reaction between sodium and water is highly exothermic, meaning it releases a large amount of heat. This is because the formation of strong ionic bonds in the products (sodium hydroxide and hydrogen gas) releases more energy than is required to break the bonds in the reactants (sodium and water). The released energy further accelerates the reaction, making it highly vigorous and sometimes explosive, particularly when large pieces of sodium are used.
The formation of sodium hydroxide (NaOH) as a product of this reaction is significant. Sodium hydroxide is a strong base and is widely used in industry for various purposes, including the manufacture of soaps, detergents, paper, and textiles. It is also used in chemical laboratories as a reagent and in the production of other chemicals.
The hydrogen gas produced during the reaction is also important. Hydrogen is a versatile and clean-burning fuel that can be used in fuel cells to generate electricity or as a source of energy in various industrial processes. In the laboratory, hydrogen gas generated from the reaction between sodium and water is often collected and used in experiments or demonstrations.
Due to the high reactivity of sodium with water, precautions must be taken when conducting this reaction. Sodium is typically stored under oil to prevent it from reacting with moisture in the air. When performing the reaction, small pieces of sodium are often used to control the rate of reaction and minimize the risk of splattering or explosions. Additionally, the reaction should be conducted in a controlled environment, such as a fume hood, to ensure safety.
Overall, the reaction between sodium and water is not only of fundamental importance in chemistry but also has practical applications in industry and research. Understanding the underlying principles of this reaction allows scientists and engineers to harness its potential for various purposes, from the production of chemicals to the generation of clean energy.